N-Methyl-2-oxo-1-phenylpropan-1-aminium chloride
نویسنده
چکیده
In the structure of the title compound, C(10)H(14)NO(+)·Cl(-), both H atoms bound to nitro-gen are involved in N-H⋯Cl hydrogen-bonding inter-actions. These inter-actions join the cations and anions into dimeric units (two cations and two anions) with R(4) (2)(8) motifs lying about inversion centers.
منابع مشابه
1-Carboxy-3-phenylpropan-2-aminium chloride
The title compound, C(9)H(12)NO(2) (+)·Cl(-), is the hydro-chloride of an N-substituted glycine derivative. The non-H atoms of the alkyl part of the mol-ecule lie nearly in a plane (r.m.s. deviation of all fitted non-H atoms = 0.0142 Å). In the crystal structure, O-H⋯Cl, N-H⋯Cl and C-H⋯O hydrogen bonds involving both O atoms as well as C-H⋯Cl contacts connect the components of the title compoun...
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In the title molecular salt, C(7)H(14)N(5)O(+)·Cl(-) (the HCl salt of the oxo derivative of the triazine herbicide simazine), the cation and anion are linked by N-H⋯Cl hydrogen bonds. The chloride ion is also involved in a close electrostatic inter-action with an inversion-related triazine ring [Cl⋯centroid distance = 3.201 (1) Å]. A π-π inter-action having a centroid⋯centroid distance of 3.456...
متن کامل1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-aminium chloride–thiourea (1/1)
In the title compound, C(11)H(14)N(3)O(+)·Cl(-)·CH(4)N(2)S, the components are connected into a two-dimensional polymeric structure parallel to (001) via N-H⋯Cl, N-H⋯O, N-H⋯S and C-H⋯S hydrogen bonds. The dihedral angle between the phenyl and 2,3-dihydro-1H-pyrazole rings is 44.96 (7)°.
متن کاملMutual prodrug of cephazolin and benzydamin: 3-[(1-benzyl-1H-indazol-3-yl)oxy]-N,N-dimethylpropan-1-aminium 3-{[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]methyl}-8-oxo-7-[(1H-tetrazol-1-yl)acetamido]-5-thia-1-azabicyclo[4.2.0]octane-2-carboxylate (benzydaminium cephazolinate)
In the crystal of the title mol-ecular salt, C(19)H(24)N(3)O(+)·C(14)H(13)N(8)O(4)S(3) (-), the cations and anions are linked by N-H⋯O hydrogen bonds. Short intra-molecular C-H⋯O contacts occur within the anion and inter-molecular C-H⋯O and C-H⋯π bonds help to establish the packing.
متن کامل3-(4-Bromophenyl)-N,N-dimethyl-3-oxopropan-1-aminium chloride
The title compound, C(11)H(15)BrNO(+)·Cl(-), was obtained as a precursor within our current program for the synthesis of new β-amino-alcohols via a Mannich-type reaction. The protonated amino N atom is hydrogen bonded to the chloride anion. With exception of one methyl group, the cation is approximately planar (r.m.s. deviation for all non H-atoms = 0.069 Å).
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011